Oh, even though I know a handful more VAs by name, I often still think of them as characters, typically the first biggest role I heard them in. I typically tend to learn the names of ones I hear over and over and over because I associate them with so many characters, or my favorites. Ironically both Steve Blum and Wendee Lee I both heard first in Cowboy Bebop, so I think of Blum as "Spike voice" most and I almost exclusively think of Lee as "Faye Valentine voice." I think of Spike Spencer (Rolo) as "Shinji Voice" and I was so excited when I heard he was playing Rolo because even though I hate him, I knew Shinji's voice would be TOO PERFECT. OTOH I was pretty surprised to hear "Vash voice" was going to be Lelouch, but now I think of Johnny Yong Bosch as "Lelouch voice" instead.